First enantioselective total synthesis and structure determination of the anthrapyran metabolite gamma-indomycinone |
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| Authors: | Tietze Lutz F Singidi Ramakrishna Reddy Gericke Kersten M |
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| Affiliation: | Institute of Organic and Biomolecular Chemistry, Georg-August-University, Tammannstrasse 2, D-37077 G?ttingen, Germany. |
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| Abstract: | The first total synthesis of (R)-gamma-indomycinone has been achieved which allowed the determination of the configuration of the stereogenic center of natural gamma-indomycinone as (S). The approach stands out for its generality and efficiency. [reaction: see text] |
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