| PdCl2/ O-MCM-41催化剂制备及其在苯酚氧化羰化反应中的应用 |
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| 引用本文： | 范国枝,李志强,黄娇,李涛,李光兴. PdCl2/ O-MCM-41催化剂制备及其在苯酚氧化羰化反应中的应用[J]. 无机化学学报, 2006, 22(9): 1701-1705 |
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| 作者姓名： | 范国枝 李志强 黄娇 李涛 李光兴 |
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| 作者单位： | 华中科技大学化学系,武汉,430074 |
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| 基金项目： | 国家高技术研究发展计划(863计划) |
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| 摘 要： | Hybrid mesoporous silica MCM-41 (O-MCM-41) was prepared using γ-aminopropyltriethoxysilane (APTES) as spacer, tetraethoxysilane as precursor and 2-acetylpyridine as organic moiety. The heterogeneous palladium catalyst (PdCl2/ O-MCM-41) was then prepared by reaction of the hybrid MCM-41 with PdCl2(PhCN)2. The products were characterized by means of IR, XRD, XPS and N2 adsorption-desorption isotherms. The catalytic properties of the supported catalyst in the oxidative carbonylation of phenol to diphenyl carbonate (DPC) were investigated. The yield of DPC and turnover number (TON) reached 5.8% and 29 mol DPC·mol Pd-1, and Pd loss was only 2.7% at 110 ℃, 4.4 MPa for catalytic reaction of 5 h with 4.2wt% Pd loading, and molar ratio of phenol to Pd being 1000 in the presence of Cu2O and terahydrofuran (THF).
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| 关 键 词： | MCM-41； 负载钯催化剂； 氧化羰化； 苯酚 |
| 文章编号： | 1001-4861（2006）09-1701-05 |
| 收稿时间： | 2006-03-28 |
| 修稿时间： | 2006-06-01 |
PdCl2 Anchored on Hybrid MCM-41: Preparation and Catalytic Application in Oxidative Carbonylation of Phenol |
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| FAN Guo-Zhi,LI Zhi-Qiang,HUANG Jiao,LI Tao and LI Guang-Xing. PdCl2 Anchored on Hybrid MCM-41: Preparation and Catalytic Application in Oxidative Carbonylation of Phenol[J]. Chinese Journal of Inorganic Chemistry, 2006, 22(9): 1701-1705 |
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| Authors: | FAN Guo-Zhi LI Zhi-Qiang HUANG Jiao LI Tao LI Guang-Xing |
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| Affiliation: | Department of Chemistry, Huazhong University of Science and Technology, Wuhan 430074,Department of Chemistry, Huazhong University of Science and Technology, Wuhan 430074,Department of Chemistry, Huazhong University of Science and Technology, Wuhan 430074,Department of Chemistry, Huazhong University of Science and Technology, Wuhan 430074 and Department of Chemistry, Huazhong University of Science and Technology, Wuhan 430074 |
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| Abstract: | |
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| Keywords: | MCM-41 anchored Pd catalyst oxidative carbonylation phenol |
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