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Extractive Recovery of Tantalum(V) and Niobium(V) with Octanol from Hydrofluoric Acid Solutions Containing Large Amounts of Titanium(IV)
Authors:Maiorov  V G  Nikolaev  A I  Sklokin  L I  Baklanova  I V
Institution:(1) Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Scientific Center, Russian Academy of Sciences, Apatity, Murmansk oblast, Russia
Abstract:Extractive recovery with n-octanol of tantalum(V) and niobium(V) from hydrofluoric acid solutions containing large amounts of titanium (up to 2-3 M) was studied. The conditions were found for separation of tantalum(V) and niobium(V) from titanium(IV), allowing recovery of 95.7 and 84.1% of tantalum and niobium fluoride complexes, respectively, in one extraction cycle, with 2.6% recovery of titanium.
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