Micro-Effects on Continuous-Injection Heat Conduction Calorimetry |
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Authors: | F Socorro M Rodríguez de Rivera |
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Institution: | (1) ETSII, Universidad de Las Palmas, Campus de Tafira, E-35017 Las Palmas de Gran Canaria, Spain |
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Abstract: | A localized-constant model involving two capacities reliably describes two injection calorimeters: a mass-variation calorimeter
and a constant-volume calorimeter (TAM 2277 by Thermometric). The model distinguishes the place and the types of dissipation,
and its parameters depend on the rates and on the heat capacities of the liquids. In the case of the TAM 2277 calorimeter,
the dependence between the detected heat of mixing and the injection rate is revealed. The proposed model permits the inclusion
of perturbations on the baseline originating from the temperature variation of the thermostat.
This revised version was published online in July 2006 with corrections to the Cover Date. |
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Keywords: | conduction calorimetry flow calorimetry liquid mixtures low concentration modelling signal processing time-dependent systems |
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