Meeting the Challenge of Intermolecular Gold(I)‐Catalyzed Cycloadditions of Alkynes and Allenes |
| |
| Authors: | Dr Michael E Muratore Anna Homs Carla Obradors Prof Antonio M Echavarren |
| |
| Institution: | 1. Institute of Chemical Research of Catalonia (ICIQ), Av. Pa?sos Catalans 16, 43007 Tarragona (Spain);2. Departament de Química Analítica i Química Orgànica, Universitat Rovira i Virgili, C/Marcel?lí Domingo s/n, 43007 Tarragona (Spain) |
| |
| Abstract: | The development of gold(I)‐catalyzed intermolecular carbo‐ and hetero‐cycloadditions of alkynes and allenes has been more challenging than their intramolecular counterparts. Here we review, with a mechanistic perspective, the most fundamental intermolecular cycloadditions of alkynes and allenes with alkenes. |
| |
| Keywords: | alkynes allenes cycloaddition gold |
|
