Vicinal Difunctionalization of Alkenes with Iodine(III) Reagents and Catalysts |
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| Authors: | R. Martín Romero Dr. Thorsten H. Wöste Prof. Dr. Kilian Muñiz |
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| Affiliation: | 1. Institute of Chemical Research of Catalonia (ICIQ), Av. Pa?sos Catalans 16, E‐43007 Tarragona (Spain), Fax: (+34)?977‐920‐224;2. Catalan Institution for Research and Advanced Studies (ICREA), Pg. Lluís Companys 23, E‐08010 Barcelona (Spain) |
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| Abstract: | Hypervalent iodine(III) reagents have been known for over a century, and their reaction profile is still actively investigated. Recent years have seen impressive improvements in the area of alkene difunctionalization reactions, where new methodologies have become available. Especially chiral non‐racemic hypervalent iodine(III) reagents and catalysts have emerged as versatile tools for the realization of important enantioselective transformations. |
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| Keywords: | alkenes asymmetric synthesis catalysis hypervalent iodine oxidation |
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