A facile and stereoselective synthesis of the C-2 epimer of (+)-deacetylanisomycin |
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| Authors: | K. Sridhar ReddyB. Venkateswara Rao |
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| Affiliation: | Organic III division, Indian Institute of Chemical Technology, Tarnaka, Hyderabad 500607, India |
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| Abstract: | A short, simple and efficient synthesis of the C-2 epimer of (+)-deacetylanisomycin starting from d-mannitol, utilizing an epoxide opening with a Grignard reagent and acid catalysed unusual intramolecular 5-endo-tet cyclization as key steps has been reported. |
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