Ruthenium catalyzed regioselective hydrophosphination of propargyl alcohols |
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| Authors: | Jérôme François Monnier Florian Lawicka Hania Dérien Sylvie Dixneuf Pierre H |
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| Affiliation: | Institut de Chimie de Rennes, UMR 6509-CNRS-Université de Rennes, Organométalliques et Catalyse, Campus de Beaulieui 35042, Rennes, France. |
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| Abstract: | Catalytic hydrophosphination of propargyl alcohols by ruthenium complexes RuCl(cod)(C5Me5) and RuCl(PPh3)2(C5Me5) leads to the formation of functionalized vinylphosphines, with linkage of the phosphorus atom to the terminal alkyne carbon, via a ruthenium vinylidene intermediate. |
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