Iminium ion catalysis: use of the alpha-effect in the acceleration of the Diels-Alder reaction |
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Authors: | Cavill Julie L Peters Jens-Uwe Tomkinson Nicholas C O |
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Affiliation: | Department of Chemistry, Cardiff University, PO Box 912, Cardiff, UK CF10 3TB. |
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Abstract: | The alpha-effect can be used in the acceleration of the Diels-Alder reaction between a series of dienes and electron deficient dienophiles using iminium ion catalysis, providing a novel molecular scaffold capable of performing this class of catalytic process. |
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