The key intermediates that interact with the fluorophores in the peroxyoxalate chemiluminescence reaction of 2,4,6-trichlorophenyl N-aryl-N-tosyloxamates |
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Authors: | Koike Ryu Motoyoshiya Jiro Takaguchi Yutaka Aoyama Hiromu |
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Affiliation: | Department of Chemistry, Faculty of Textile Science & Technology, Shinshu University, Ueda, Nagano 386-8567, Japan. |
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Abstract: | A kinetic study of peroxyoxalate chemiluminescence reactions employing 2,4,6-trichlorophenyl N-aryl-N-tosyloxamates supports the 1,2-dioxetanones still bearing the eliminating group as the key intermediates that interact with the fluorophores rather than 1,2-dioxetanedione. |
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