A novel access to 3-aryl-2-norbornyl cation |
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| Authors: | Mella Mariella Esposti Silvia Fagnoni Maurizio Albini Angelo |
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| Affiliation: | Department of Organic Chemistry, University of Pavia, via Taramelli 10, 27100 Pavia, Italy. |
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| Abstract: | A novel access to a 2-norbornyl cation under mild, non acidic conditions is found in the addition of photochemically generated 4-dimethylaminophenyl cation to 2-norbornene. Deprotonation to nortricyclene or nucleophile addition ensue depending on the solvent characteristics. |
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