Reversible C-C bond formation: solid state structure of the aldol-like addition product of adamantanone to a 1,5-diazapentadienyllithium,and its solution state retro-aldol dissociation |
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| Authors: | Ball Lee-Jon Dickie Anthony P Mair Francis S Middleton David A Pritchard Robin G |
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| Institution: | Department of Chemistry, UMIST, PO Box 88, Manchester, UK M60 1QD. |
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| Abstract: | Analysis of crystals of the lithium complex of the tripodal ligand formed upon addition of adamantanone to a 1,5 diazapentadienyllithium complex reveals a long C-C bond which ruptures upon dissolution in non-co-ordinating solvents. |
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