A novel synthetic strategy for hexanuclear supramolecular architectures |
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Authors: | Dolomanov Oleg V Blake Alexander J Champness Neil R Schröder Martin Wilson Claire |
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Affiliation: | School of Chemistry, The University of Nottingham, University Park, Nottingham, UK NG7 2RD. |
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Abstract: | Hexanuclear cage complexes [M6L6X](X)5 [M = Cu(I), Ag(I); L = 6,6'-bis(4-ethynylpyridine)2,2'-bipyridine; X = BF4-, SbF6-] have been prepared using a self-assembly approach; these architectures encapsulate anions in the solid-state and are fluxional in solution. |
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