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A novel synthetic strategy for hexanuclear supramolecular architectures
Authors:Dolomanov Oleg V  Blake Alexander J  Champness Neil R  Schröder Martin  Wilson Claire
Institution:School of Chemistry, The University of Nottingham, University Park, Nottingham, UK NG7 2RD.
Abstract:Hexanuclear cage complexes M6L6X](X)5 M = Cu(I), Ag(I); L = 6,6'-bis(4-ethynylpyridine)2,2'-bipyridine; X = BF4-, SbF6-] have been prepared using a self-assembly approach; these architectures encapsulate anions in the solid-state and are fluxional in solution.
Keywords:
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