HNC-type approximation for transport processes in electrolytic solutions |
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Authors: | Dietrich Kremp Werner Ebeling Hartmut Krienke Rainer SÄndig |
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Affiliation: | (1) Sektion Physik der Wilhelm-Pieck-UniversitÄt Rostock, 2500 Rostock, Germany;(2) Sektion Physik der Humboldt-UniversitÄt zu Berlin, 1040 Berlin, Germany |
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Abstract: | On the basis of the diffusion approach in the theory of transport processes of electrolytic solutions we introduce a direct correlation force as a generalization of the direct correlation function in equilibrium. Starting from an approximation for the three-particle distribution function we derive a HNC (hypernetted chain)-type equation for calculation of binary distribution functions in nonequilibrium. The derivation is consistent with equilibrium theory. |
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Keywords: | Transport processes electrolytic conductance diffusion approach direct correlation force HNC equation |
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