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Interactions of vibrationally excited CO2 with oxygen and sulfur atoms
Authors:T M Grigor'eva  A A Levitskii  L S Polak  R L Tatuzov
Institution:(1) Topchiev Petrochemical Synthesis Institute, USSR Academy of Sciences, Moscow
Abstract:The classical-path method has been used in calculations on O+CO2 rarr CO+ O2 and S+CO2 rarr CO+SO for vibrational-translational disequilibrium. The vibrational-energy localization in various modes in CO2 affects the reaction cross section and rate constant. The energy distributions in the products have been calculated.Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 24, No. 4, pp. 428–434, July–August, 1988.
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