Studies in vinyl chloride polymerization. Determination of primary radical termination by initiator fragment method |
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Authors: | Ebhodaghe F Okieimen |
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Institution: | Department of Chemistry, University of Wales Institute of Science and Technology, Cardiff CF1 3NU, U.K. |
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Abstract: | The rate of vinyl chloride polymerization initiated by doubly labelled benzoyl peroxide in dichloroethane at 60° was measured dilatometrically. The extent of primary radical termination, evaluated from the assay of the polymer samples recovered at 10% conversion, is compared with values deduced from analysis of the kinetic data. |
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