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Studies in vinyl chloride polymerization. Determination of primary radical termination by initiator fragment method
Authors:Ebhodaghe F Okieimen
Institution:Department of Chemistry, University of Wales Institute of Science and Technology, Cardiff CF1 3NU, U.K.
Abstract:The rate of vinyl chloride polymerization initiated by doubly labelled benzoyl peroxide in dichloroethane at 60° was measured dilatometrically. The extent of primary radical termination, evaluated from the assay of the polymer samples recovered at 10% conversion, is compared with values deduced from analysis of the kinetic data.
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