Asymmetric catalytic synthesis of the proposed structure of trocheliophorolide B |
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| Authors: | Barry M Trost Adrien Quintard |
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| Institution: | Department of Chemistry, Stanford University , Stanford, California 94305-5080, United States. |
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| Abstract: | A concise catalytic asymmetric synthesis of the proposed structure of trocheliophorolide B is reported. The synthetic sequence notably features an asymmetric acetaldehyde alkynylation, a Ru-catalyzed alder-ene reaction, and a Zn-ProPhenol ynone aldol condensation. Comparison with the reported data suggests a misassignment of the natural product structure. |
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