Structure and reactivity of a novel parallel thiosulfito (SSO2-S:S') rhodium dinuclear complex |
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| Authors: | Shiomi Kimie Breedlove Brian K Kitayama Hiroaki Nishioka Takanori Kinoshita Isamu Koga Nobuaki Isobe Kiyoshi |
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| Institution: | Department of Material Science, Graduate School of Science, Osaka City University, Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan. |
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| Abstract: | The parallel thiosulfite ligand (SSO2) in a rhodium complex, which is formed by oxygenation of a bridging disulfide, is converted to a bridging hydrocarbyl thiolate ligand and sulfur dioxide gas by the reaction with hydrocarbyl halides. |
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