Tandem isomerization/Claisen transformation of allyl homoallyl and diallyl ethers into gamma,delta-unsaturated aldehydes with a new three component catalyst Ru3(CO)12/imidazolinium salt/Cs2CO3 |
| |
| Authors: | Le Nôtre Jérôme Brissieux Luc Sémeril David Bruneau Christian Dixneuf Pierre H |
| |
| Institution: | Institut de Chimie de Rennes, UMR 6509 CNRS-Université de Rennes, Organométalliques et Catalyse, Campus de Beaulieu, 35042 Rennes, France. |
| |
| Abstract: | The three component catalyst Ru3(CO)12/1,3-bis(2,6-diisopropylphenyl)imidazolinium chloride/Cs2CO3 (molar ratio 1:3:6) successively promotes both allyl to vinyl isomerization and Claisen rearrangement from allyl homoallyl and diallyl ethers to selectively afford gamma,delta-unsaturated aldehydes. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
