Synthesis and coordination chemistry of a water-soluble verdazyl radical. structures and magnetic properties of M(H2O)2(vdCO2)(2).2H2O (M = Co,Ni; vdCO2 = 1,5-dimethyl-6-oxo-verdazyl-3-carboxylate) |
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Authors: | Barclay Tosha M Hicks Robin G Lemaire Martin T Thompson Laurence K Xu Zhiqiang |
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Affiliation: | Department of Chemistry, North Harris College, Houston, Texas 77073, USA. |
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Abstract: | The synthesis of a verdazyl radical with a carboxylate substituent renders the radical highly soluble in water, thereby permitting the aqueous synthesis of Ni(II) and Co(II) verdazyl complexes which have been structurally and magnetically characterized. |
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