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Polyoxometalate immobilized on MOF‐5 as an environment‐friendly catalyst for the synthesis of poly‐functionalized 3‐pyrrolin‐2‐ones |
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| Authors: | Li Bao‐Le Hong‐Yan Zhang Jia‐Qi Di Zhan‐Hui Zhang |
| Abstract: | A polyoxometalate immobilized on MOF‐5 (POM/MOF‐5) material has been synthesized and evaluated for the diversity‐oriented synthesis of poly‐functionalized 3‐pyrrolin‐2‐ones via pseudo‐four‐component reaction between dialkyl acetylenedicarboxylate, amines, and aldehyde. The catalyst can be separated from the reaction mixture and reused at least five times with superior activity. |
| Keywords: | 3‐pyrrolin‐2‐ones heterogeneous catalyst MOF‐5 multicomponent reaction polyoxometalate |