Transition metal complexes with cage-opened diamondoid tetracyclo[7.3.1.14,12.02,7]tetradeca-6.11-diene |
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| Authors: | Lars Valentin Anja Henss Boryslav A Tkachenko Andrey Fokin Peter R Schreiner Sabine Becker |
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| Institution: | 1. Institute of Inorganic and Analytical Chemistry, Justus-Liebig University, Gie?en, Germany;2. Institute of Organic Chemistry, Justus-Liebig University, Gie?en, Germany;3. Department of Organic Chemistry, Kiev Polytechnic Institute, Kiev, Ukraine |
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| Abstract: | Cage-opened diamondoid tetracyclo7.3.1.14,12.02,7]tetradeca-6,11-diene forms complexes with AgNO3 and CuCl. The latter crystallized from acetonitrile in polymeric form Cu2Cl2(CH3CN)(diene)]n; in the presence of 2,2′-bipyridine, a double-charged monomeric Cu(I)-complex Cu2(bipy)2(diene)]2+ formed. Both complexes were structurally characterized through X-ray crystal diffraction analysis. |
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| Keywords: | Copper complexes Coordination polymers Diamantane Diamondoid Nanodiamonds Diene |
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