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Speciation of lead in soils and relation with its concentration in fruits
Authors:Mehmet Yaman   Yusuf Dilgin  Seref Gucer
Affiliation:

a Firat University, Sciences and Arts Faculty Department of Chemistry, Elazig, Turkey

b 18 Mart University, Sciences and Arts Faculty Department of Chemistry, Canakkale, Turkey

c Uludag University, Sciences and Arts Faculty Department of Chemistry, Bursa, Turkey

Abstract:The lead concentrations of the fruit samples were determined by using slotted tube atom trap (STAT)-enrichment-flame and graphite furnace atomic absorption spectrometry (FAAS and GF-AAS). The soil samples related to these fruits were also analysed for Pb after extraction with various chemical reagents. The relation between the fruit-lead and soil-extractable lead concentrations was examined in order to explain the bioavailability of lead. A linear relation was observed between the hot Na2EDTA extraction-soluble Pb contents in the soil and the Pb concentrations in the mulberry (R2=0.95), strawberry and apple grown on these soils. Probable chemical forms of lead in soil were evaluated. Acceptable agreement (at least 91%) was achieved between the results of STAT-enrichment-FAAS and GF-AAS.
Keywords:Speciation   Lead   Soil   Fruit   AAS
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