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Synthesis and photophysical properties of poly(aryleneethynylene)s containing dibenzosilole unit
Authors:Qiang Yanga  Liang Chun Lib  Shu Hong Lic  Dong Mei Yuea  Cai Hong Xub  a Beijing University of Chemical Technology  Beijing  China b Institute of Chemistry  Chinese Academy of Sciences  Beijing  China c
Institution:Beijing University of Chemical Technology, Beijing 100029, China. ; Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China ; Department of Chemistry, School of Science, Beijing Technology and Business University, Beijing 100048, China
Abstract:A series of poly(arylenethynylene)s containing dibenzosilole unit has been synthesized by palladium-catalyzed Sonogashira cross-coupling reactions with 2,7-diethynyl-9,9-dihexyl-3,6-dimethoxy-9H-dibenzosilole (4) as the key monomer. Their photo- physical properties in solution were investigated. All of the polymers showed intense fluorescence with high quantum efficiencies.
Keywords:Poly(arylenethynylene)s  Dibenzosilole  Sonogashira cross-coupling  Photophysics  
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