| Cu（OAc）2/Pyrimidines-Catalyzed Cross-coupling Reactions of Aryl Iodides and Activated Aryl Bromides with Alkynes under Aerobic, Solvent-free and Palladium-free Conditions |
| |
| 引用本文： | 谢叶香,邓辰亮,皮少锋,李金恒,尹笃林.Cu（OAc）2/Pyrimidines-Catalyzed Cross-coupling Reactions of Aryl Iodides and Activated Aryl Bromides with Alkynes under Aerobic, Solvent-free and Palladium-free Conditions[J].中国化学,2006,24(10):1290-1294. |
| |
| 作者姓名： | 谢叶香 邓辰亮 皮少锋 李金恒 尹笃林 |
| |
| 作者单位： | Key Laboratory of Chemical Biology ＆ Traditional Chinese Medicine Research, Ministry of Education, College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha, Hunan 410081, China |
| |
| 基金项目： | Project supported by the Key Project of Chinese Ministry of Education （No. 206102）, Fok Ying Dong Education Foundation （No. 101012）, Scientific Research Fund of Hunan Provincial Education Department （No. 05B038）, Hunan Provincial Natural Science Foundation of China （No. 05JJ1002） and the National Natural Science Foundation of China （Nos. 20572020 and 20202002） |
| |
| 摘 要： | Excellent results have been achieved in the Cu（OAc）2-catalyzed Sonogashira cross-couplings of aryl iodides and activated aryl bromides utilizing TBAF （tetrabutylammonium fluoride） as the base and 4,6-dimethoxypyrimidin-2-amine as the ligand. It is noteworthy that the reaction is conducted under aerobic, solvent-free and palladium-free conditions.
|
| 关 键 词： | Cu（OAc）2 4 6-二甲氧基嘧啶-2-胺 交叉耦合反应 芳基碘化物 芳基溴化物 炔 需氧反应 钯 |
| 收稿时间： | 2006-04-14 |
| 修稿时间： | 2006-04-142006-07-05 |
Cu(OAc)_2/Pyrimidines-Catalyzed Cross-coupling Reactions of Aryl Iodides and Activated Aryl Bromides with Alkynes under Aerobic,Solvent-free and Palladium-free Conditions |
| |
| XIE Ye-Xiang, DENG Chen-Liang, PI Shao-Feng, LI Jin-Heng,YIN Du-Lin.Cu(OAc)_2/Pyrimidines-Catalyzed Cross-coupling Reactions of Aryl Iodides and Activated Aryl Bromides with Alkynes under Aerobic,Solvent-free and Palladium-free Conditions[J].Chinese Journal of Chemistry,2006,24(10):1290-1294. |
| |
| Authors: | XIE Ye-Xiang DENG Chen-Liang PI Shao-Feng LI Jin-Heng YIN Du-Lin |
| |
| Abstract: | Excellent results have been achieved in the Cu(OAc)_2-catalyzed Sonogashira cross-couplings of aryl iodides and activated aryl bromides utilizing TBAF(tetrabutylammonium fluoride)as the base and 4,6-dimethoxypyrimidin-2-amine as the ligand.It is noteworthy that the reaction is conducted under aerobic,sol- vent-free and palladium-free conditions. |
| |
| Keywords: | Cu(OAc)_2 4 6-dimethoxypyrimidin-2-amine Sonogashira cross-coupling reaction aerobic solvent-free palladium-free |
| 本文献已被 CNKI 维普 等数据库收录！ |
