| 开叉毛细管HG-FAAS测定地质样品中的锑、铋 |
| |
| 引用本文： | 陈丽,温晓东,吴鹏,吕弋,侯贤灯. 开叉毛细管HG-FAAS测定地质样品中的锑、铋[J]. 化学研究与应用, 2007, 19(5): 567-570 |
| |
| 作者姓名： | 陈丽 温晓东 吴鹏 吕弋 侯贤灯 |
| |
| 作者单位： | 四川大学化学学院,四川,成都,610064;四川大学分析测试中心,四川,成都,610064;四川大学化学学院,四川,成都,610064;四川大学分析测试中心,四川,成都,610064 |
| |
| 摘 要： | 氢化物发生原子吸收法(HG-FAAS)广泛应用于冶金、地质、环境、医药和食品分析等领域中。研究表明,氢化物发生法的检出限、测定精度以及干扰等情况与原子化器和氢化物发生器的结构以及传输过程有关[1]。郭小伟等[2-4]研制了用于火焰原子吸收光谱分析的双毛细管喷雾器,并利用其测
|
| 关 键 词： | 锑 铋 HG FAAS 开叉毛细管 地质样品 |
| 文章编号： | 1004-1656（2007）05-0567-04 |
| 收稿时间： | 2006-09-18 |
| 修稿时间： | 2007-01-15 |
Determination of Sb and Bi in geological samples by HG-FAAS with branched capillary as hydride generator |
| |
| CHEN Li,WEN Xiao-dong,WU Peng,LV Yi,HOU Xian-deng. Determination of Sb and Bi in geological samples by HG-FAAS with branched capillary as hydride generator[J]. Chemical Research and Application, 2007, 19(5): 567-570 |
| |
| Authors: | CHEN Li WEN Xiao-dong WU Peng LV Yi HOU Xian-deng |
| |
| Abstract: | A branched capillary was investigated as an online hydride generator for the determination of Sb and Bi by hydride generation FAAS.The experimental parameters,including factors affecting hydride generation and the interferences from transition metal ions,were studied in detail.Compared with conventional FAAS,the sensitivity of the proposed HG-FAAS for Sb and Bi was improved by more than one order of magnitude.Limits of detection(LOD) were 0.03 mg/L and 0.02 mg/L for Sb and Bi,respectively.Calibration curves were linear up to 10.0 mg/L for Sb and 5.0 mg/L for Bi,respectively.The proposed method was applied to the determination of Sb and Bi in standard geological samples. |
| |
| Keywords: | Sb Bi hydride generation flame atomic absorption spectrometry branched capillary geological samples |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
