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流动注射pH梯度技术-卡尔曼滤波分光光度法同时测定铜钴镍多元混合物
引用本文:毛东森,张国莹,陈同岳. 流动注射pH梯度技术-卡尔曼滤波分光光度法同时测定铜钴镍多元混合物[J]. 化学研究与应用, 1994, 0(2)
作者姓名:毛东森  张国莹  陈同岳
作者单位:上海工业大学化学化工系,中国石油化工总公司上海石油化工研究院
基金项目:上海自然科学基金,上海市高教局基金
摘    要:流动注射pH梯度技术-卡尔曼滤波分光光度法同时测定铜钴镍多元混合物毛东森,张国莹,陈同岳(上海工业大学化学化工系,上海,200072)关键词:流动注射分析,梯度技术,卡尔曼滤波,分光光度法,同时测定探索不经任何分离而同时测定多个相互干扰组分混合物的分...

关 键 词:流动注射分析,梯度技术,卡尔曼滤波,分光光度法,同时测定

THE SiIMULTANEOUS SPECTROPHOT-METRIC DETERMINATION OF COPPER,COBALT AND NICKEL IN THEIR MIXTURES BY FIA pH GRADOENT TECHNIQUE AND KALMAN FILTER
Mao Dongsen, Zhang Guoying ,Chen Tingyue. THE SiIMULTANEOUS SPECTROPHOT-METRIC DETERMINATION OF COPPER,COBALT AND NICKEL IN THEIR MIXTURES BY FIA pH GRADOENT TECHNIQUE AND KALMAN FILTER[J]. Chemical Research and Application, 1994, 0(2)
Authors:Mao Dongsen   Zhang Guoying   Chen Tingyue
Abstract:This paper covers the Simultaneous determinations of coppet,cobalt and nickel in their binary and ternary mixtures by pH gradient technique in flow injection analysis with RAR as the chro mogenic reagent. Kalman filter is used to analyze the data provided by this method. the recoveries of the method are 95-105% and 94-108%for binary and temacy mixtures respectively.The rel ative standard deviations are lass than 2.5%.
Keywords:Flow injection analysis  Gradient technique  Kalman filter   Spectrophotomety  Si multaneous determination.
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