Synthesis of phenothiazine-corrole dyads: the enhanced DNA photocleavage properties |
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| Authors: | Lei Shi Kai-Mei Peng Li-Li You Lei Zhang Liang-Nian Ji |
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| Institution: | a School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, PR China
b State Key Laboratory of Optoelectronics Materials and Technologies/MOE Laboratory of Bioinorganic and Synthetic Chemistry, Sun Yat-Sen University, Guangzhou 510275, PR China |
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| Abstract: | Three new phenothiazine-corrole dyads were prepared by the reaction of phenothiazine-10-carbonyl chloride and mono-hydroxyl triaryl corrole in the presence of DBU. As compared to corrole monomer, these phenothiazine-corrole dyads exhibit significant enhanced DNA photocleavage activity as compared to corrole monomer precursors. |
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