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Highly efficient and regioselective allylic amination of allylic alcohols catalyzed by [Mo3PdS4] cluster |
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| Authors: | Yinsong Tao Jingping Qu Masanobu Hidai |
| Institution: | a State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116012, China b Department of Materials Science and Technology, Faculty of Industrial Science and Technology, Tokyo University of Science, Noda, Chiba 278-8510, Japan |
| Abstract: | A highly efficient and regioselective allylation reaction of amines with allylic alcohols under mild conditions catalyzed by the cubane-type sulfido cluster (Cp∗Mo)3S4Pd(dba)]PF6] with H3BO3 as an additive has been developed. A variety of amines and allylic alcohols are investigated, and in the case of allylic alcohols bearing substituents at either α- or γ-position only linear allylic amination products are obtained. |
| Keywords: | Allylic alcohol Allylation Cubane-type sulfido cluster Boric acid |
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