Magnetically separable Fe3O4 nanoparticles: an efficient catalyst for the synthesis of propargylamines |
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Authors: | B Sreedhar A Suresh Kumar P Surendra Reddy |
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Institution: | Inorganic and Physical Chemistry Division, Indian Institute of Chemical Technology (Council of Scientific and Industrial Research), Hyderabad 500607, India |
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Abstract: | Magnetically separable Fe3O4 nanoparticles endow with an efficient and economic route for the synthesis of propargylamines by the three-component coupling of aldehyde, amine, and alkyne through C-H activation. The reaction is especially effective for reactions involving aliphatic aldehydes and no additional co-catalyst or activator is required. High catalytic activity and ease of recovery using an external magnetic field are additional eco-friendly attributes of this catalytic system. The catalyst was recycled for five times without a significant loss of catalytic activity. |
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Keywords: | Propargylamines Magnetically separable Fe3O4 nanoparticles Terminal alkynes Amines Aldehydes |
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