Luminescent properties of dicyanoaurate(I) aggregates based on electrostatic assembly along poly(allylamine hydrochloride) |
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Authors: | Toshiyuki Moriuchi |
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Affiliation: | Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamada-oka, Suita, Osaka 565 0871, Japan |
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Abstract: | Poly(allylamine hydrochloride) (PAA) bearing positively charged side chains along the polymer chain was demonstrated to serve as a polymeric spatially aligned scaffold for aggregation and self-association of negatively charged [Au(CN)2]− through the electrostatic and aurophilic bonding interactions to afford the luminescent [Au(CN)2]− aggregates. |
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