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Luminescent properties of dicyanoaurate(I) aggregates based on electrostatic assembly along poly(allylamine hydrochloride)
Authors:Toshiyuki Moriuchi
Affiliation:Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamada-oka, Suita, Osaka 565 0871, Japan
Abstract:Poly(allylamine hydrochloride) (PAA) bearing positively charged side chains along the polymer chain was demonstrated to serve as a polymeric spatially aligned scaffold for aggregation and self-association of negatively charged [Au(CN)2] through the electrostatic and aurophilic bonding interactions to afford the luminescent [Au(CN)2] aggregates.
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