Bi2O3-catalyzed oxidation of aldehydes with t-BuOOH |
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Authors: | Payal Malik |
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Institution: | Department of Chemistry, Indian Institute of Technology Madras, Chennai 600 036, Tamil Nadu, India |
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Abstract: | A variety of aromatic, aliphatic and conjugated aldehydes were transformed to the corresponding carboxylic acids with 70% t-BuOOH solution (water) in the presence of catalytic amounts of Bi2O3. This method possesses a wide range of capabilities, does not involve cumbersome work-up, exhibits chemoselectivity and proceeds under mild conditions. The resulting products are obtained in good yields within reasonable time. The overall method is green. |
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Keywords: | Oxidation Aldehyde Acid Bi2O3 t-BuOOH |
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