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Oryzamutaic acids H-J, new alkaloids from an Oryza sativa mutant with yellow endosperm
Authors:Hiroshi Nakano  Seiji Kosemura  Rika Iwaura  Ryota Kaji
Affiliation:a National Agricultural Research Center for Kyushu Okinawa Region, Chikugo, Fukuoka 833-0041, Japan
b Department of Chemistry, Hiyoshi Campus, Keio University, Kohoku-ku, Yokohama 223-8521, Japan
c National Food Research Institute, Tsukuba, Ibaraki 305-8642, Japan
d Faculty of Agriculture, Kagawa University, Miki, Kagawa 761-0795, Japan
Abstract:Three new nitrogen-containing heterocyclic alkaloids, oryzamutaic acids H-J (1-3), were isolated from the endosperm (polished rice) of an Oryza sativa mutant. The structures and relative stereochemistries of 1-3 were elucidated on the basis of spectroscopic analyses. The presence of three carbons, each bound to a carboxyl group and a nitrogen atom in the structure of 1, suggests that oryzamutaic acids H-J (1-3) are generated from three molecules of a single amino acid.
Keywords:Oryza sativa   Poaceae   Alkaloid   Oryzamutaic acids H-J
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