Oryzamutaic acids H-J, new alkaloids from an Oryza sativa mutant with yellow endosperm |
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Authors: | Hiroshi Nakano Seiji Kosemura Rika Iwaura Ryota Kaji |
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Affiliation: | a National Agricultural Research Center for Kyushu Okinawa Region, Chikugo, Fukuoka 833-0041, Japan b Department of Chemistry, Hiyoshi Campus, Keio University, Kohoku-ku, Yokohama 223-8521, Japan c National Food Research Institute, Tsukuba, Ibaraki 305-8642, Japan d Faculty of Agriculture, Kagawa University, Miki, Kagawa 761-0795, Japan |
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Abstract: | Three new nitrogen-containing heterocyclic alkaloids, oryzamutaic acids H-J (1-3), were isolated from the endosperm (polished rice) of an Oryza sativa mutant. The structures and relative stereochemistries of 1-3 were elucidated on the basis of spectroscopic analyses. The presence of three carbons, each bound to a carboxyl group and a nitrogen atom in the structure of 1, suggests that oryzamutaic acids H-J (1-3) are generated from three molecules of a single amino acid. |
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Keywords: | Oryza sativa Poaceae Alkaloid Oryzamutaic acids H-J |
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