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Design and characterization of ferrocene-peptide-oligoaniline conjugates
Authors:Toshiyuki Moriuchi
Affiliation:Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamada-oka, Suita, Osaka 565-0871, Japan
Abstract:Ferrocene-peptide-oligoaniline conjugates were designed by the introduction of two ferrocene-peptide conjugates into a π-conjugated phenylenediamine spacer to demonstrate the luminescent switching by changing the redox states of the π-conjugated phenylenediamine moiety, wherein the self-aggregation of the π-conjugated moiety was achieved in a higher concentration to induce the chirality organization with a red shift of the maximum emission wavelength.
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