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First stereoselective total synthesis of decarestrictine O via RCM protocol |
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| Authors: | Palakodety Radha Krishna T Jagannadha Rao |
| Institution: | D-211, Discovery Laboratory, Organic Chemistry Division-III, Indian Institute of Chemical Technology, Hyderabad 500 607, India |
| Abstract: | A convergent first stereoselective total synthesis of decarestrictine O via RCM protocol starting from 1,3-propanediol and propylene oxide is reported. |
| Keywords: | Decarestrictine O Propylene oxide Jacobsen hydrolytic kinetic resolution Sharpless asymmetric epoxidation Yamaguchi esterification Grubbs&rsquo II generation catalyst |
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