A convenient synthetic route to furan esters and lactones by palladium-catalyzed carboalkoxylation or cyclocarbonylation of hydroxyl-substituted 3-iodofurans |
| |
| Authors: | Chul-Hee Cho |
| |
| Affiliation: | Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States |
| |
| Abstract: | An effective palladium-catalyzed protocol for the intermolecular carboalkoxylation or intramolecular cyclocarbonylation of hydroxyl-substituted 3-iodofurans under carbon monoxide pressure has been developed. The 3-iodofurans are readily prepared by iodocyclization of 2-(1-alkynyl)-2-alken-1-ones in the presence of various diols. |
| |
| Keywords: | Palladium Iodocyclization Carbonylation Furan |
| 本文献已被 ScienceDirect 等数据库收录！ |
