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Iron-catalyzed selective reduction of nitro compounds to amines |
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| Authors: | Leyla Pehlivan,Sté phane Laval,Patrice Demonchaux,Marc Lemaire |
| Affiliation: | a Laboratoire de Catalyse, Synthèse et Environnement, Institut de Chimie et Biochimie Moléculaires et Supramoléculaires (ICBMS), CNRS, UMR5246, Université Lyon 1, 43 Boulevard du 11 Novembre 1918, Bât CPE, 69622 Villeurbanne, France b Minakem SAS, 145 Chemin des Lilas, 59310 Beuvry la Foret, France c Rhodia, Lyon Research Center, 85 Avenue des Frères Perret, BP 62, 69192 Saint-Fons Cedex, France |
| Abstract: | An efficient reduction of the nitro group with a catalytic amount of Fe(acac)3 and TMDS in THF at 60 °C affording the corresponding amine is described. |
| Keywords: | Reduction Nitro Amines 1,1,3,3-Tetramethyldisiloxane Iron catalyst |
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