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Synthesis and photophysical properties of chiral dendrimers with quinoline surface group via click chemistry
Authors:Perumal Rajakumar  Rathinam Raja
Institution:Department of Organic Chemistry, University of Madras, Guindy Campus, Chennai 600 025, Tamil Nadu, India
Abstract:Synthesis of some novel chiral dendrimers containing quinoline as surface group and 1,2,3-triazole as branching unit is described. The chiroptical property exhibits the widening of the torsional angle in the BINOL core as the generation increases. The photophysical properties indicate an increase in the molar extinction coefficient and fluorescence intensity and a decrease in quantum yield and lifetime as the generation of the dendrimer increases.
Keywords:Click chemistry  Quinoline  Chiral S-(&minus  )-BINOL  Alkynes  Azide  1  2  3-Triazole
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