Rh(II) catalysts with 4-hydroxyproline-derived ligands |
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| Authors: | Hanne Therese Bonge |
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| Institution: | Department of Chemistry, University of Oslo, Sem Sælands vei 26, N-0315 Oslo, Norway |
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| Abstract: | Three new chiral Rh(II) catalysts with 4-hydroxyproline-derived ligands have been synthesised through a short and efficient synthetic route. The catalysts give good yields and ees in C-H insertion and cyclopropanation reactions, and their properties indicate an all-up reactive conformation of proline- and 4-hydroxyproline-derived Rh(II) catalysts. |
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