PRODUCTION OF VINYL CHLORIDE IN THE INFRARED LASER INDUCED PHOTOSENSITIZED CHAIN REACTION OF 1, 2-DICHLOROETHANE |
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| Authors: | Ju Lin LIU Pei Hua MA Guan Cheng CHEN |
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| Institution: | The Institute of Saline Lakes Chinese Academy of Sciences Xining Qinghai 810008 |
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| Abstract: | The chain reaction of 1, 2-dichloroethane was initiated by photosensitization of SF6 under the selective excitation using a cw CO2 laser.Vinyl chloride with high purity was produced in the reaction process.The initiation of the photosensitized chain reaction depends on the irradiated laser frequency.The mechanism of intermolecularr esonant transfer of vibrational energy has been discussed. |
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