| 诺贝尔化学奖类大学生创新实验——Suzuki偶联反应制备DPP类荧光染料 |
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| 摘 要： |
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| 关 键 词： | 诺贝尔化学奖 Suzuki偶联反应 吡咯并吡咯二酮 荧光 |
| 收稿时间： | 2019-11-25 |
Innovative Experiment for Students Based on Nobel Prizes in Chemistry: Construction of Fluorescent DPP Derivative by Suzuki Reaction |
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| Jiukai Xiong,Meijuan Zhao,Yanan Wang,Gang Bian,Ruixue Rong,Kerang Wang. Innovative Experiment for Students Based on Nobel Prizes in Chemistry: Construction of Fluorescent DPP Derivative by Suzuki Reaction[J]. University Chemistry, 1986, 35(12): 227-232. DOI: 10.3866/PKU.DXHX201911053 |
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| Authors: | Jiukai Xiong Meijuan Zhao Yanan Wang Gang Bian Ruixue Rong Kerang Wang |
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| Affiliation: | 1. Key Laboratory of Medicinal Chemistry and Molecular Diagnosis(Ministry of Education), College of Chemistry and Environmental Science, Hebei University, Baoding 071002, Hebei Province, P. R. China;2. Department of Immunology, School of Basic Medical Science, Hebei University, Baoding 071000, Hebei Province, P. R. China |
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| Abstract: | Fluorescent diketopyrrolopyrrole (DPP) derivative was synthesized by coupling reaction, nucleophilic substitution reaction and Suzuki reaction, which was fully characterized by NMR spectroscopy and HRMS. Furthermore, the DPP derivative showed high fluorescence quantum yields of 88.4% and 78.9% in solvent and solid states. |
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| Keywords: | Nobel Prizes in chemistry Suzuki coupling reaction Diketopyrrolopyrrole Fluorescence |
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