Crystal Structure of the Sought-After Tetrameric [(PDBP)AgCl]4 Cluster (PDBP=5-Phenyldibenzophosphole) |
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| Authors: | Hong Zhang J. Jiang N. Yang H. Dang Boon K. Teo |
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| Affiliation: | (1) Department of Chemistry, University of Illinois at Chicago, Chicago, Illinois, 60607;(2) Department of Chemistry, Beijing Polytechnic University, Beijing, 100022, PRC |
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| Abstract: | The sought-after member of the [(PDBP)nAgX]m (n, m=1,4; 2,2; 3,1; PDBP=5-Phenyldibenzophosphole, X=halides) series, the tetrameric [(PDBP)AgCl]4 cluster has been prepared and structurally characterized. The [P4Ag4Cl4] cluster core of [(PDBP)AgCl]4 bears striking similarity to that of [(Ph3P)AgCl]4. |
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| Keywords: | Silver cluster crystal structure tetrameric cluster |
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