Bidentate ligands formed by self-assembly |
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| Authors: | Slagt Vincent F van Leeuwen Piet W N M Reek Joost N H |
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| Affiliation: | Institute of Molecular Chemistry, University of Amsterdam, Nieuwe Achtergracht 166, Amsterdam, The Netherlands. |
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| Abstract: | A novel supramolecular strategy to prepare bidentate ligands via the assembly of functionalised monomeric ligands on a dimeric zinc(II) porphyrin template is presented; the assembled bidentate ligands show chelating behaviour and their rhodium complexes display enhanced selectivity in the hydroformylation compared to the non-template analogue. |
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