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Model systems for flavoenzyme activity: flavin-functionalised SAMs as models for probing redox modulation through hydrogen bonding
Authors:Cooke Graeme  Duclairoir Florence M A  John Phillip  Polwart Neil  Rotello Vincent M
Institution:Centre for Biomimetic Design & Synthesis, Chemistry, William H. Perkin Building, School of Engineering & Physical Sciences, Heriot-Watt University, Riccarton, Edinburgh, UK EH14 4AS.
Abstract:We report the fabrication of flavin-functionalised self-assembled monolayers upon gold electrodes and their subsequent redox modulation via hydrogen bonding to 2,6-diethylamidopyridine.
Keywords:
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