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Substitution of a bridgehead bromide by primary organolithium reagents |
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| Authors: | Harmata Michael Wacharasindhu Sumrit |
| Institution: | Department of Chemistry, University of Missouri-Columbia, Columbia, Missouri 65211, USA. harmatam@missouri.edu |
| Abstract: | The reaction of ketone 1 with primary organolithium reagents in THF/HMPA affords not the expected carbonyl addition product but the product of bromide substitution, in reasonable yield. |
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