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Metal-assisted red light-induced efficient DNA cleavage by dipyridoquinoxaline-copper(II) complex
Authors:Dhar Shanta  Senapati Dulal  Reddy Pattubala A N  Das Puspendu K  Chakravarty Akhil R
Institution:Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560012, India.
Abstract:Complete cleavage of double stranded pUC19 DNA by the complex Cu(dpq)2(H2O)](ClO4)2 (dpq, dipyridoquinoxaline) has been observed on irradiation at 694 nm from a pulsed ruby laser, assisted by the metal d-band transition as well as the quinoxaline triplet states in the absence of any external additives.
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