An organopalladium chromogenic chemodosimeter for the selective naked-eye detection of Hg(2+) and MeHg(+) in water-ethanol 1 : 1 mixture |
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Authors: | Del Campo O Carbayo A Cuevas J V Muñoz A García-Herbosa G Moreno D Ballesteros E Basurto S Gómez T Torroba T |
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Affiliation: | Departamento de Química, Universidad de Burgos, 09001 Burgos, Spain. |
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Abstract: | An organopalladium chemical dosimeter of Hg(2+) that methylates Hg(2+), undergoing a colour change in 1 : 1 ethanol-water with submicromolar sensitivity, gives rise to an aqua-palladium complex that is methylated by MeHg(+) in the presence of a dithiol compound, undergoing another colour change, thus making the system suitable for the naked-eye detection of Hg(2+) and MeHg(+), two environmentally important species of Hg(2+). |
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