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Mechanism of methanol decomposition by non-thermal plasma
Authors:Marzie Derakhshesh  Jalal Abedi  Hassan Hassanzadeh
Institution:Department of Chemical and Petroleum Engineering, University of Calgary, Schulich School of Engineering, 2500 University Drive, N.W., Calgary, AB, Canada T2N 1N4
Abstract:In this investigation available experimental data in the literature were used to propose a reaction mechanism for the destruction of methanol using non-thermal plasma technology. In a recent study M. Derakhshesh, J. Abedi, M. Omidyeganeh, Modeling of hazardous air pollutant removal in the pulsed corona discharge, Phys. Lett. A 373 (2009) 1051–1057.] the reactor performance equation for destruction of pollutants was developed. The order of reaction for methanol decomposition is estimated using a recently developed performance model and the available experimental data. It is found that that methanol decomposition reaction follows order one. In addition, using the experimental data available in the literature the rate constant for methanol decomposition is obtained and the overall rate was compared with our previous study.
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