Transient shear rheology of carbon nanofiber/polystyrene melt composites |
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| Authors: | Christopher Kagarise Jianhua Xu Yingru Wang Monon Mahboob Kurt W. Koelling Stephen E. Bechtel |
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| Affiliation: | 1. Department of Materials Chemistry and Chemical Technology, Institute of Chemistry, University of Silesia, 40-006 Katowice, Szkolna 9, Poland;2. School of Pharmacy with the Division of Laboratory Medicine in Sosnowiec, Medical University of Silesia, Department of Physical Pharmacy, 41-200 Sosnowiec, Jagiellońska 4, Poland;1. National Institute of Standards and Technology, Gaithersburg, Maryland 20899;2. Departments of Mechanical Engineering, Chemistry and Biochemistry, University of Maryland, College Park, Maryland 20742 |
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| Abstract: | We characterize the transient shear rheology of polystyrene/carbon nanofiber composites. Our experimental measurements of the composites show increasing stress overshoot responses to transient shear as the carbon nanofiber concentration increases. We also find the steady state viscosity reached at long times during application of a constant shear rate increases with increasing carbon nanofiber concentration. Flow reversal experiments show the effects of nanofiber orientation and structural evolution on the composite's rheological response.We present a microstructurally based constitutive model where all but two parameters are determined by rheological characterization of the pure polymer and the shape and concentration of the nanoparticles. The Folgar-Tucker constant, CI, is treated as a fitting parameter, while several definitions for the shape factors A, B, C and F are evaluated. We make note of the effects each parameter has on the model's predictions. We find that the constitutive model is in agreement with our experimentally measured transient shear rheology of the PS/CNF melt composites for the CNF concentrations and shear rates presented. |
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